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Electrochemical Strategy for Proton Relay Installation Enhances the Activity of a Hydrogen Evolution Electrocatalyst

https://doi.org/10.1021/jacs.2c06011

Lin, Shaoyang ; Banerjee, Samragni ; Fortunato, Matthew T. ; Xue, Congcong ; Huang, Jie ; Sokolov, Alexander Yu. ; Turro, Claudia ( November 2022 , Journal of the American Chemical Society)

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Synthetic Strategies for Trapping the Elusive trans -Dirhodium(II,II) Formamidinate Isomer: Effects of Cis versus Trans Geometry on the Photophysical Properties

https://doi.org/10.1021/acs.inorgchem.9b02966

Millet, Agustin ; Xue, Congcong ; Song, Ellen ; Turro, Claudia ; Dunbar, Kim R. ( February 2020 , Inorganic Chemistry)
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Electron injection into titanium dioxide by panchromatic dirhodium photosensitizers with low energy red light

https://doi.org/10.1039/c9cc04677a

Xue, Congcong ; Sayre, Hannah J. ; Turro, Claudia ( August 2019 , Chemical Communications)

Two new Rh 2 ( ii , ii ) dyes were synthesized and anchored to TiO 2 for charge injection upon irradiation. The 1 ML-LCT (metal/ligand-to-ligand charge transfer) excited state is populated upon excitation, which decays to the corresponding 3 ML-LCT state. Ultrafast electron injection into TiO 2 from the Rh 2 ( ii , ii ) dyes was achieved with low energy, red light excitation.
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